{2,2′-[(5-Bromopyridine-2,3-diyl)bis(nitrilomethylidyne)]diphenolato}chlorido(N,N-dimethylformamide)iron(III)
نویسندگان
چکیده
In the title complex, [Fe(C(19)H(12)BrClN(3)O(2))(C(3)H(7)NO)], the Fe(III) atom is coordinated by an N,N,O,O-tetra-dentate Schiff base ligand and trans coordinated by a chloride anion and the O atom of an N,N-dimethyl-formamide mol-ecule. The resulting geometry is distorted octa-hedral within a ClN(2)O(3) donor set.
منابع مشابه
{2,2′-[5-Bromopyridine-2,3-diylbis(nitrilomethylidyne)]diphenolato}chlorido(dimethylformamide)manganese(III)
In the title complex, [Mn(C(19)H(12)BrN(3)O(2))Cl(C(3)H(7)NO)], the Mn(III) ion is coordinated by two N and two O atoms from the tetra-dentate Schiff base ligand, one O atom from the dimethyl-formamide ligand and a Cl anion in a distorted octa-hedral geometry. In the crystal structure, weak inter-molecular C-H⋯Cl hydrogen bonds link the mol-ecules into centrosymmetric dimers with a short distan...
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